Quantitative Reasoning

1015SCG

Lecture 2


Units of measurement

Units

  • In Australia, we use the
    International System of Units
    SI, from French Système International d'unités.
  • It is composed by seven fundamental units, known as SI base units.


Source: A Brief History of the Metric System by Carmen J. Giunta (2023).

Units

SI base units
Unit Physical quantity
Symbol Name
s Second Time
m Metre Length
kg Kilogram Mass
A Ampere Electric current
K Kelvin Thermodynamic temperature
mol Mole Amount of substance
cd Candela Luminous intensity

Source: A Brief History of the Metric System by Carmen J. Giunta (2023).


Units: Other physical quantities

Any other physical quantities can be written as some combination of these base units, and are sometimes are given their own name.

  • $\text{velocity}= \dfrac{\text{distance}}{\text{time}}$ $=\dfrac{\text{m}}{\text{s}}$
  • $\text{acceleration}= \dfrac{\text{velocity}}{\text{time}}$ $=\dfrac{\text{m}/\text{s}}{\text{s}}$ $=\dfrac{\text{m}}{\text{s}^2}$
  • $\text{force}= \text{mass}\times \text{acceleration}$ $=\text{kg}\times \dfrac{\text{m}}{\text{s}^2}$ $=\text{N}$ $\;\; $(Newton)
  • $\text{pressure}= \dfrac{\text{force}}{\text{area}}$ $= \dfrac{\text{N}}{\text{m}^2}$ $= \dfrac{\text{kg}\times \dfrac{\text{m}}{\text{s}^2}}{\text{m}^2}$ $= \dfrac{\text{kg}}{\text{m}\times\text{s}^2}$ $= \text{Pa}$ $\;\;$(Pascal)
  • $\text{energy}= \text{mass}\times \text{velocity}^2$ $= \text{kg} \times \dfrac{\text{m}^2}{\text{s}^2}$ $= \dfrac{\text{kg}\times \text{m}^2}{\text{s}^2}$ $= \text{J}$ $\;\;$(Joule)

Other sets of units

There are a number of non-SI units accepted for use alongside SI units, e.g.:

  • Angle in degrees, minutes and seconds (e.g. latitude and longitude).
  • Area in hectares.
  • Volumes in litres.
  • Time in minutes, hours, days, years.
  • Temperature in degrees Celsius.



Other sets of units

People in the U.S. uses customary units in daily life (related to the British Imperial system), e.g.:

  • Lengths in inches, feet, yards, miles and area in acres.
  • Mass in pounds.
  • Temperatures in degrees Fahrenheit (F)
  • Ounces (oz) for mass and fluid ounces (fl oz) for volume.




Metric and Imperial system

Image source: Statista: Metric or Imperial? (2019)


πŸ“ Practice: Examples

1. The length of the stick is measured to be 70 cm. But you want to communicate with your American friend. How many inches it is?
    Hint: 1 inch = 2.54 cm.

2. The pasture is a rectangle with dimensions of 500 m by 2 km. How many hectares it is?
    Hint: 1 ha = 100 m Γ— 100 m.

3. An Olympic swimming pool has dimensions 50 m Γ— 25 m Γ— 2 m. How many liters of water it can fit?
    Hint: 1 L = 10 cm Γ— 10 cm Γ— 10 cm.

4. The conversion from Fahrenheit to Celsius degrees is \(^{\circ}\text{C} = \dfrac{5}{9}\left(^{\circ}\text{F}-32\right).\) Find
      (a) \(\,0^\circ\text{F}\) in \(^\circ \text{C},\qquad\) (b) \(\, 100^\circ\text{F} \) in \(^\circ\text{C},\qquad\) (c) \(\, -40^\circ\text{C} \) in \(^\circ\text{F}\)


πŸ“ Practice: Examples

1. The length of the stick is measured to be 70 cm. But you want to communicate with your American friend. How many inches it is?
    Hint: 1 inch = 2.54 cm.

We need a conversion factor! Since we know that 1 inch = 2.54 cm, then

\( \dfrac{\text{1 inch}}{\text{2.54 cm}} = 1 \)   πŸ‘ˆ This is a conversion factor!

Thus we have

\(70 \text{ cm}\) \(=70 \text{ cm} \times 1\) \(=70 \text{ cm} \times \dfrac{\text{1 inch}}{\text{2.54 cm}} \) \(= \dfrac{70}{2.54} \text{ inch}\) \(= 27.56 \text{ inch}\)



πŸ“ Practice: Examples

2. The pasture is a rectangle with dimensions of 500 m by 2 km. How many hectares is it?
  Hint: 1 ha = 100 m Γ— 100 m.

Let's start by finding the area in square metres. First, we knot that \(2\,\text{km} = 2000\,\text{m}\)

Area = \(500 \text{ m} Γ— 2\,000 \text{ m} \) \(= 1\,000\,000 \text{ m}^2\)

Now use the conversion factor from $\text{m}^2$ β†’ $\text{ha}$:

\(1 \text{ ha} = 100 \text{ m} Γ— 100 \text{ m} \) \(= 10\,000 \text{ m}^2\)
\(\dfrac{1 \text{ ha}}{10\,000 \text{ m}^2} = 1\)  πŸ‘ˆ Conversion factor

\(1\,000\,000 \text{ m}^2 Γ— \dfrac{1 \text{ ha}}{10\,000 \text{ m}^2} \) \(= 100 \text{ ha}\)


πŸ“ Practice: Examples

3. An Olympic swimming pool has dimensions 50 m Γ— 25 m Γ— 2 m. How many litres of water can it fit?
  Hint: 1 L = 10 cm Γ— 10 cm Γ— 10 cm = 1 000 cmΒ³ = 0.001 mΒ³

First, find the volume in cubic metres.

Volume = \(50\text{ m} Γ— 25\text{ m} Γ— 2 \text{ m}\) \(= 2\,500 \text{ m}^3\)

Now use the conversion between cubic metres and litres:

\(1 \text{ m}^3 = 1\,000 \text{ L}\)
\(\dfrac{1\,000 \text{ L}}{1 \text{ m}^3} = 1\)  πŸ‘ˆ Conversion factor

\(2\,500 \text{ m}^3 Γ— \dfrac{1\,000 \text{ L}}{1 \text{ m}^3} \) \(= 2\,500\,000 \text{ L}\)


πŸ“ Practice: Examples

4. The conversion from Fahrenheit to Celsius degrees is \(^{\circ}\text{C} = \dfrac{5}{9}\left(^{\circ}\text{F}-32\right).\) Find:
    (a) \(0^\circ\text{F}\) in \(^{\circ}\text{C},\qquad\) (b) \(100^\circ\text{F}\) in \(^{\circ}\text{C},\qquad\) (c) \(-40^\circ\text{C}\) in \(^{\circ}\text{F}\)

πŸ’«(a) For \(0^\circ\text{F}\) in \(^{\circ}\text{C}\): \(\; ^{\circ}\text{C} = \dfrac{5}{9}(0 - 32) \) \(= \dfrac{5}{9}(-32)\) \(= -17.78^{\circ}\text{C}\)

πŸ’«(b) For \(100^{\circ}\text{F}\): \(\;^{\circ}\text{C} = \dfrac{5}{9}(100 - 32)\) \( = \dfrac{5}{9}(68)\) \(= 37.78^{\circ}\text{C}\)

πŸ’«(c) Now convert \(-40^{\circ}\text{C}\) to \(^{\circ}\text{F}\), use the inverse formula: \(^{\circ}\text{F} = \dfrac{9}{5}{}^{\circ}\text{C} + 32\)

Thus \(\; ^{\circ}\text{F} = \dfrac{9}{5}(-40) + 32\) \( = -72 + 32 \) \( = -40^{\circ}\text{F}\)

So, at \(-40^{\circ}\), Celsius and Fahrenheit are equal! ❄️


πŸ“ More practice πŸ˜ƒ

- Cheetahs can reach speeds up to 120 km/h.

  • How fast is it in m/s?
  • What about feet/quarter-hour? (1 foot $\approx$ 30 cm)

- I can paint a wall with the speed of 0.2 $\dfrac{\text{m}^2}{\text{min}}$.

  • How long will it take me to paint a 5 m $\times$ 3 m wall?


πŸ“ More practice πŸ˜ƒ

- Cheetahs can reach speeds up to 120 km/h.

  • How fast is it in m/s?
  • What about feet/quarter-hour? (1 foot β‰ˆ 30 cm)

πŸ‘‰ \(120 \text{ km/h} = 120{,}000 \text{ m}/3{,}600 \text{ s} = 33.3 \text{ m/s}\)

πŸ‘‰ \(120 \text{ km/h} = 120{,}000 \text{ m/h} = 400{,}000 \text{ ft/h}\) β‡’ \( 100{,}000 \text{ ft}/ \text{quarted-hour}\)

- I can paint a wall with the speed of 0.2 \(\dfrac{\text{m}^2}{\text{min}}\).

  • How long will it take me to paint a 5 m Γ— 3 m wall?

πŸ‘‰ Wall area = \(5\text{ m} \times 3\text{ m} = 15 \text{ m}^2\). Then Time = \(\dfrac{15 \text{ m}^2 }{0.2\frac{\text{m}^2}{\text{min}}} = 75 \text{ min} = 1\text{ h }15\text{ min}\)



Why getting it right is important...

The Gimli Glider was an Air Canada Boeing 767 that ran out of fuel mid-flight in 1983 due to a metric conversion errorβ€”the fuel was loaded in pounds instead of kilograms. The pilots glided the plane safely to an emergency landing at a former airbase in Gimli, Manitoba, with no fatalities.


⚠️ Other Famous Conversion Errors

Mars Climate Orbiter (1999): Lost because of a mismatch between imperial and metric units (pound-seconds vs newton-seconds). See Mars climate orbiter
Space Mountain, Tokyo Disneyland (2003): Roller coaster axle failed after parts were made using inch instead of millimeter specifications. See Unit Mixups

Final remarks about the SI

SI base units (1960)
Unit Physical quantity
Symbol Name
s second Time
m Metre Length
kg Kilogram Mass
A Ampere Electric current
K Kelvin Thermodynamic temperature
mol Mole Amount of substance
cd Candela Luminous intensity

Source: A Brief History of the Metric System by Carmen J. Giunta (2023).



Final remarks about the SI

SI base units (2019)
Unit Defining constant
Symbol Name
s Second Frequency of Caesium-133
hyperfine transition (ΔνCs)
m Metre Speed of light in vacuum (c)
kg Kilogram Planck constant (h)
A Ampere Elementary charge (e)
K Kelvin Boltzmann constant (k)
mol Mole Avogadro constant (NA)
cd Candela Luminous efficacy of
540Γ—1012 Hz radiation (Kcd)

Source: A Brief History of the Metric System by Carmen J. Giunta (2023).



Scientific Notation, Orders of Magnitude

Image source: visualcapitalist.com


The decimal system


The decimal system

\(= \mathbf 7\times 10 ^3 \) \(+\,\mathbf 5\times 10 ^2 \) \(+\,\mathbf 9\times 10 ^1 \) \(+\,\mathbf 4\times 10 ^0 \)

\(\qquad+\,\mathbf 1\times 10 ^{-1} \) \(+\,\mathbf 6\times 10 ^{-2} \) \(+\,\mathbf 3\times 10 ^{-3} \)



Really small things

Radius of a helium atom:

  $0.000\,000\,000\,031 \text{ m}$

   $= 3.1 \times 10^{-11} \text{ m}$

Size of a helium nucleus (alpha particle):

  $0.000\,000\,000\,000\,000\,002 \text{ m}$

   $= 2 \times 10^{-18} \text{ m}$

Mass of a helium atom:

  $0.000\,000\,000\,000\,000\,000\,000\,000\,006\,64 \text{ kg}$

   $= 6.64 \times 10^{-27} \text{ kg}$

Really big things

Galactic orbit of our sun:

  $230\,000\,000 \text{ years}$

   $=2.3 \times 10^{8} \text{ years}$

The size (diameter) of our galaxy:

  $950\,000\,000\,000\,000\,000\,000 \text{ m}$

   $ = 9.5 \times 10^{20}\text{ m}$

Total mass of stars in the universe:

  $200\,000\,000\,000\,000\,000\,000$ ✨ $\times$

  $2\,000\,000 \,000\,000\,000\,000\,000\,000\,000\,000 \text{ kg}$

  $ =\left(2\times 10^{20} \times 2 \times 10^{30} \text{ kg}\right)$ $=4\times 10^{50} \text{ kg}$


Normilised Scientific Notation


$ \pm a \times 10 ^{n}$


  • $a$ - is called significand, with $\,1\leq a\lt 10$
  • $n$ - is the exponent (integer number)


Normilised Scientific Notation

$ \pm a \times 10 ^{n}$

  • $10^{-n}$ $=0.\overbrace{000\cdots000}^{n-1\ \text{ zeros}}1$
  • $10^{-3}$ $=0.001$
  • $10^{-2}$ $=0.01$
  • $10^{-1}$ $=0.1$

  • $10^{1}$ $=10$
  • $10^{2}$ $=100$
  • $10^{3}$ $=1000$
  • $10^{n}$ $=1\underbrace{000\cdots000}_{n\ \text{ zeros}}$


Writing numbers in normalised scientific notation

  1. Determine how many places you need to move the decimal point to get a significand at least 1 but less than $10.$
  2. Determine the exponent:
    • If you move the decimal point to the left, the exponent is positive.
    • If you move the decimal point to the right, the exponent is negative.
  3. Write the number in the form $a\times 10^{n}.$

Example 1: $142.14$

$142.14 = 1.4214 \times 10^{2}$

Example 2: $0.0312$

$0.0312 = 3.12 \times 10^{-2}$

βœ… Normalised form: one non-zero digit before the decimal point.


Writing numbers in normalised scientific notation

πŸ’» Calculator/Computer notation

$142.14 = 1.4214 \times 10^{2}$

$\quad \;\,=1.4214\text{E}2$ πŸ‘ˆ


$0.0312 = 3.12 \times 10^{-2}$

$\qquad \;\,\;\,=3.12\text{E}-2$ πŸ‘ˆ



πŸ“ Write in scientific notation πŸ˜ƒ

1. Height of Q1 Tower: $322.5\ \text{m}$


2. Diameter of the Moon: $3\,474\,800\ \text{m}$


3. Average mass of an E.coli cell (wet): $0.000\,000\,000\,001\ \text{g}$


4. Distance between carbon atoms in diamond: $0.000\,000\,000\,154\,4\ \text{m}$



πŸ“ Write in scientific notation πŸ˜ƒ

1. Height of Q1 Tower: $322.5\ \text{m}$

$$\textbf{Ans. } 3.225 \times 10^{2}\ \text{m}$$


2. Diameter of the Moon: $3\,474\,800\ \text{m}$

$$\textbf{Ans. } 3.4748 \times 10^{6}\ \text{m}$$


3. Average mass of an E.coli cell (wet): $0.000\,000\,000\,001\ \text{g}$

$$\textbf{Ans. } 1 \times 10^{-12}\ \text{g}$$


4. Distance between carbon atoms in diamond: $0.000\,000\,000\,154\,4\ \text{m}$

$$\textbf{Ans. } 1.544 \times 10^{-10}\ \text{m}$$


SI Metric Prefixes

Prefix Symbol Base 10 Decimal Name
peta P 1015 1 000 000 000 000 000 quadrillion
tera T 1012 1 000 000 000 000 trillion
giga G 109 1 000 000 000 billion
mega M 106 1 000 000 million
kilo k 103 1 000 thousand
hecto h 102 100 hundred
deca da 101 10 ten
base unit - 100 1 one
deci d 10-1 0.1 tenth
centi c 10-2 0.01 hundredth
milli m 10-3 0.001 thousandth
micro Β΅ 10-6 0.000 001 millionth
nano n 10-9 0.000 000 001 billionth
pico p 10-12 0.000 000 000 001 trillionth
femto f 10-15 0.000 000 000 000 001 quadrillionth
Powers of Ten


Example using SI Metric Prefixes

p n Β΅ m c d da h k M G
$10^{-12}$ $10^{-9}$ $10^{-6}$ $10^{-3}$ $10^{-2}$ $10^{-1}$ $10^{1}$ $10^{2}$ $10^{3}$ $10^{6}$ $10^{9}$

The distance between carbon atoms in diamond is

$\quad 0.000\,000\,000\,154\,4\ \text{m}$

First, convert to normalized scientific notation

$\quad 0.000\,000\,000\,154\,4\ \text{m} $ $= 1.544 \times 10^{-10}\ \text{m}\;$

                 Not in the SI Metric Prefixes‼️ πŸ‘†

But we can write as: $\, 0.1544 \times 10^{-9}\ \text{m} $ $= 0.1544 \, \text{nm} $

βœ… The carbon-carbon distance in diamond is $0.1544 $ nm

$\left(154.4\times 10^{-12}\right)$ πŸ‘‰ or also $154.4 $ pm



Example using SI Metric Prefixes

The distance between carbon atoms in diamond is

$\quad 0.000\,000\,000\,154\,4\ \text{m}$

First, convert to normalized scientific notation

$\quad 0.000\,000\,000\,154\,4\ \text{m} $ $= 1.544 \times 10^{-10}\ \text{m}\;$

If we want to use normalized scientific notation, we can write this in Γ…ngstrΓΆms (a unit of length).

We just need to use the conversion factor: 1 Γ… = $10^{-10}$ m

$\quad 1.544 \times 10^{-10}\ \text{m} $ $= 1.544\ \text{Γ…}$

βœ… The carbon-carbon distance in diamond is $1.544$ Γ…



πŸ“ Write using SI Metric PrefixesπŸ˜ƒ

p n Β΅ m cm d da h k M G
$10^{-12}$ $10^{-9}$ $10^{-6}$ $10^{-3}$ $10^{-2}$ $10^{-1}$ $10^{1}$ $10^{2}$ $10^{3}$ $10^{6}$ $10^{9}$

1. Age of a dinosaur fossil: $70\,000\,000\ \text{years}=$ _____ Myears


2. Height of Q1 Tower: $322.5\ \text{m}=$ _____ hm = _____ km


3. Diameter of the Moon: $3\,474\,800\ \text{m}=$ ________Mm


4. Average mass of an E.coli cell (wet): $0.000000000001\ \text{g}=$ _____ pg



πŸ“ Write using SI Metric Prefixes πŸ˜ƒ

p n Β΅ m cm d da h k M G
$10^{-12}$ $10^{-9}$ $10^{-6}$ $10^{-3}$ $10^{-2}$ $10^{-1}$ $10^{1}$ $10^{2}$ $10^{3}$ $10^{6}$ $10^{9}$

1. Age of a dinosaur fossil: $70\,000\,000\ \text{years}=$ _____ Myears

$\quad 7 \times 10 ^{7} \text{ years}$ $ = 70 \times 10^6 \text{ years}$ $ = 70 \text{ Myears}$


2. Height of Q1 Tower: $322.5\ \text{m}=$ $3. 225 \text{ hm}$ $= 0.3225 \text{ km}$

$\quad 3.225 \times 10^{2} \text{ m}$ $ = 0.3225 \times 10^{3} \text{ m}$


3. Diameter of the Moon: $3\,474\,800\ \text{m} = 3.4748\ \text{Mm}$


4. Average mass of an E.coli cell (wet): $0.000000000001\ \text{g} = 1\ \text{pg}$



Orders of magnitude β€” From trillion to trillionth

Common name SI prefix (symbol) Decimal Power of ten Order of magnitude
Trillion tera (T) 1 000 000 000 000 1012 +12
Billion giga (G) 1 000 000 000 109 +9
Million mega (M) 1 000 000 106 +6
Thousand kilo (k) 1 000 103 +3
One (none) 1 100 0
Tenth deci (d) 0.1 10βˆ’1 βˆ’1
Hundredth centi (c) 0.01 10βˆ’2 βˆ’2
Thousandth milli (m) 0.001 10βˆ’3 βˆ’3
Millionth micro (Β΅) 0.000 001 10βˆ’6 βˆ’6
Billionth nano (n) 0.000 000 001 10βˆ’9 βˆ’9
Trillionth pico (p) 0.000 000 000 001 10βˆ’12 βˆ’12

Orders of magnitude

When values vary across a broad scale, it is helpful to think in terms of the exponent $m$, which we call an order of magnitude β€” $\log_{10}(10^m)$

Image source: Chem 1 Virtual Textbook by Stephen Lower


Recap

Scientific notation or SI Prefixes to convey very small or very large quantities.

f p n Β΅ m cm
$10^{-15}$ $10^{-12}$ $10^{-9}$ $10^{-6}$ $10^{-3}$ $10^{-2}$

h k M G T P
$10^{2}$ $10^{3}$ $10^{6}$ $10^{9}$ $10^{12}$ $10^{15}$

πŸ‘‰ Scientific notation ⇔ SI prefixes




All together now!

πŸš€

🧩 Polya’s Problem-Solving Heuristics

  • Understand the problem β€” Identify what is known, what is unknown, and the conditions.
  • Devise a plan β€” Look for connections to similar problems, use patterns, draw diagrams, simplify, or work backwards.
  • Carry out the plan β€” Execute the strategy carefully, checking each step.
  • Look back β€” Verify results, reflect on the method, and consider generalizations.


Source: How To Solve It, by George Polya, 2nd ed., Princeton University Press, 1957.


πŸ“ Converting between units & relations using units

  1. What is the height of the Q1 Tower (322.5 m) in microns? $(1\text{ micron} = 1 \,\mu \text{m})$
  2. What is the age of the universe (1.38 Γ— 10¹⁰ years) in minutes?
  3. What is the speed of light (3 Γ— 10⁸ m/s) in AU/hour?

    AU is known as the Astronomical Unit, the average distance between Sun and Earth. 1 AU = $150$ billion meters (billion = $10^9$).

  4. If a single Tic Tac contains approximately 2 kilocalories (kcal), how long would it take to burn off the calories?

    (a) If sitting $(65 \text{ kcal}/\text{hour})$     (b) If dancing $(150 \text{ kcal}/\text{hour})$




🏒 Q1 Tower Height

What is the height of the Q1 Tower (322.5 m) in microns? $(1\text{ micron} = 1 \,\mu \text{m})$

$1 \text{ metre} = 1 \,000\, 000 \text{ microns }(\mu \text{m})$

$\dfrac{ 1 \,000\, 000 \,\mu\text{m}}{1 \text{ m}} = 1$  πŸ‘ˆ Conversion factor

$\qquad\qquad 322.5 \text{ m}$ $=322.5 \text{ m} \times \dfrac{ 1 \,000\, 000 \,\mu\text{m}}{1 \text{ m}}$

$\qquad\qquad \qquad \quad =3.225 \times 10^{2} \times 10^{6} \,\mu\text{m}$

$\qquad\qquad \qquad \quad =3.225 \times 10^{8} \,\mu\text{m}$




🌌 Age of the Universe

What is the age of the universe (1.38 Γ— 10¹⁰ years) in minutes?

1 year = 365 days = 365 Γ— (24 hours)            

= 365 Γ— 24 Γ— (60 mins) = 525 600 mins

1 year = 525 600 mins  πŸ‘ˆ Conversion

1.38 Γ— 10¹⁰ years = (1.38 Γ— 10¹⁰) Γ— 525 600 mins $\qquad \qquad \qquad \quad $

= 1.38 Γ— 10¹⁰ Γ— 5.256 Γ— 10⁡ mins = 7.25328 Γ— 10¹⁡ mins

πŸ€” What value do you get if you consider 1 year = 365.25 day?



⚑ Speed of Light in AU/hour

What is the speed of light (3 Γ— 10⁸ m/s) in AU/hour?

πŸ‘‰ $ $ 1 AU = 1.5 Γ— 10ΒΉΒΉ m = 150 billion meters

πŸ‘‰ 1 hour = 3 600 seconds$\qquad\qquad $

$3 \times 10^{8}\,\dfrac{\text{m}}{\text{s}}$ $= 3 \times 10^{8}\,\dfrac{\text{m}}{\text{s}} \times 3\,600\,\dfrac{\text{s}}{\text{hour}} $ $= 3 \times 10^{8} \times 3\,600\,\dfrac{\text{m}}{\text{hour}} $

$\qquad = 3 \times 10^{8} \times 3\,600\,\dfrac{\text{m}}{\text{hour}} \times \dfrac{1}{1.5\times 10 ^{11}}\, \dfrac{\text{AU}}{\text{m}} $

$\qquad = 3 \times 10^{8} \times 3\,600 \times \dfrac{1}{1.5\times 10 ^{11}}\, \dfrac{\text{AU}}{\text{hour}} $ $= \dfrac{(3\times 3.6) \times 10^{11}}{1.5\times 10 ^{11}}\, \dfrac{\text{AU}}{\text{hour}} $

$\qquad= \dfrac{3\times 3.6 }{1.5}\, \dfrac{\text{AU}}{\text{hour}} $ $= 7.2\, \dfrac{\text{AU}}{\text{hour}} $


πŸ”₯ Burning a Tic Tac

If one Tic Tac β‰ˆ 2 kilocalories (kcal), how long to burn it off?

(a) Sitting: $65\,\dfrac{\text{kcal}}{\text{hour}}$ = Rate of burning calories

πŸ‘‰ $\;\text{Rate} = \dfrac{\text{Energy}}{\text{Time}}$ $\;\Ra\; \text{Time} =\dfrac{\text{Energy}}{\text{Rate}}$

Thus $\,\text{Time} = \dfrac{2 \,\text{kcal}}{65\,\frac{\text{kcal}}{\text{hour}}}$ $=\dfrac{2}{65}\,\text{hours}$ $\approx 0.0308\,\text{hours}$ $=1.85\,\text{minutes}$

(b) Dancing: $150\,\dfrac{\text{kcal}}{\text{hour}}$ β†’ $\text{Time} = 0.0133\,\text{hours} \approx 0.8 \,\text{mins}$



βš›οΈ Mole & Molar mass

Mole (unit)

The mole (mol) is a unit of measurement, the base unit in the SI for amount of substance, an SI base quantity proportional to the number of elementary entities of a substance.

$1\, \text{mol} = 6.022\,140\,76 \times 10^{23}\, \text{entities}$

Molar mass

The molar mass (M) of a chemical substance (element or compound) is defined as the ratio between the mass (m) and the amount of substance (n, measured in moles) of any sample of the substance:

$\text{M} = \dfrac{\text{mass of the substance}}{\text{number of moles of the substance}}$


βš—οΈ Description of solutions

Concentration of the solution (g/L)

$\text{Concentration}=\dfrac{\text{mass of the solute}} {\text{volume of the solution}}$


Molar concentration - morality (mol/L)

$\text{Morality}=\dfrac{\text{numbers of moles of solute}} {\text{volume of the solution}}$



βš—οΈ Other concentrations

\(\%\text{w/w}\) - weight per weight concentration - how many \(\text{g}\) of the solute there are in \(100 \, \text{g}\) of the solution

$\% \dfrac{\text{w}}{\text{w}}=\dfrac{\text{mass of the solute in g}} {100\,\text{g of the solution}}\times 100 \%$

\(\%\text{w/v}\) - weight per volume concentration - how many \(\text{g}\) of the solute there are in \(100 \, \text{ml}\) of the solution

$\% \dfrac{\text{w}}{\text{v}}=\dfrac{\text{mass of the solute in g}} {100\,\text{ml of the solution}}\times 100 \%$

\(\%\text{v/v}\) - volume per volume concentration - how many ml of the solute are there in \(100 \, \text{ml}\) of the solution

$\% \dfrac{\text{v}}{\text{v}}=\dfrac{\text{mass of the solute in ml}} {100\,\text{ml of the solution}}\times 100 \%$



πŸ“ Extra practice πŸ˜€

1. What is the concentration and molar concentration of the 0.444 mol of cobalt chloride $\text{CoCl}_2$ in 0.654 L of solution (129.839 g/mol)?

2. A patient has a serum (39.0983 g/mol) level of 3 mmol/L.
  (a) How many mmol are present in a 50 ml sample?
  (b) How many mg are present in a 50 ml sample?

3. A glucose solution contains 10% w/v of glucose in water. How much glucose is in 1L of the solution?

4. What weight of hydrochloric acid is needed to produce 50 g of 30% w/w acid?



πŸ“ Extra practice πŸ˜€

1. What is the concentration and molar concentration of the 0.444 mol of cobalt chloride $\text{CoCl}_2$ in 0.654 L of solution (129.839 g/mol)?

  πŸ’«Ans. Mass concentration = 88.15 g/L;   Molar concentration = 0.6790 mol/L.

2. A patient has a serum (39.0983 g/mol) level of 3 mmol/L.
  (a) How many mmol are present in a 50 ml sample?
  (b) How many mg are present in a 50 ml sample?

  πŸ’«Ans. (a) 0.150 mmol. (b) 5.865 mg.

3. A glucose solution contains 10% w/v of glucose in water. How much glucose is in 1L of the solution?

  πŸ’«Ans. 100 g glucose per 1 L.

4. What weight of hydrochloric acid is needed to produce 50 g of 30% w/w acid?

  πŸ’«Ans. 15 g HCl (to make 50 g of 30% w/w).



πŸ“ Extra practice - Solutions

1. What is the concentration and molar concentration of the 0.444 mol of cobalt chloride $\text{CoCl}_2$ in 0.654 L of solution (129.839 g/mol)?

  1. Molar concentration (M): \(C = \dfrac{\text{moles}}{\text{volume (L)}} = \dfrac{0.444\ \text{mol}}{0.654\ \text{L}}\).
  2. Calculate: \(C = \dfrac{0.444\ \text{mol}}{0.654\ \text{L}}= 0.678899\ \text{mol / L}\). Rounded to four decimals: $0.6790 \,\text{mol / L}$
  3. Mass of solute: \(m = n \times M = 0.444\ \text{mol} \times 129.839\ \text{g / mol} = 57.6485\ \text{g}.\)
  4. Mass concentration $(\text{g/L})$: \(\rho = \dfrac{m}{V} = \dfrac{57.6485\ \text{g}}{0.654\ \text{L}} = 88.1476\ \text{g / L}.\) Rounded: \(88.15 \,\text{g / L}\)

Thus, Mass concentration = \(88.15 \,\text{g / L}\); Molar concentration = $0.6790 \,\text{mol / L}$.


πŸ“ Extra practice - Solutions

2. A patient has a serum (39.0983 g/mol) level of 3 mmol/L.
  (a) How many mmol are present in a 50 ml sample?
  (b) How many mg are present in a 50 ml sample?

  1. Convert volume to litres: \(50\ \text{mL} = 0.050\ \text{L}.\)
  2. (a) Amount in mmol: \(n_{\text{mmol}} = C(\text{mmol / L}) \times V(\text{L}) = 3\ \text{mmol / L}\times 0.050\ \text{L} = 0.150\ \text{mmol}.\)
  3. (b) Mass in mg: 1 mmol corresponds to \(M\,/ \,1000\) g = \(39.0983\ \text{mg}\).
    So \(m(\text{mg}) = 0.150\ \text{mmol} \times 39.0983\ \text{mg / mmol} = 5.864745\ \text{mg}.\)
    Rounded: 5.865 mg.

Thus, (a) 0.150 mmol; (b) 5.865 mg.



πŸ“ Extra practice - Solutions

3. A glucose solution contains 10% w/v of glucose in water. How much glucose is in 1L of the solution?

  1. Definition: 10% w/v means 10 g of solute per 100 mL of solution.
  2. Scale to 1000 mL (1 L): \( \dfrac{10\ \text{g}}{100\ \text{mL}} \times 1000\ \text{mL} = 100\ \text{g}.\)

Thus, the answer is 100 g glucose per 1 L of solution.





πŸ“ Extra practice - Solutions

4. What weight of hydrochloric acid is needed to produce 50 g of 30% w/w acid?

  1. 30% w/w means mass fraction of solute = 0.30 (i.e. 30 g HCl per 100 g solution).
  2. Mass of pure HCl required: \(m_{\text{HCl}} = 0.30 \times 50\ \text{g} = 15\ \text{g}.\)
  3. To prepare the 50 g solution you would combine 15 g HCl with 35 g solvent (usually water) to give a total mass of 50 g.

Hence, the answer is 15 g HCl (to make 50 g of 30% w/w solution).



That's all for today!

See you in Week 3!